X. M. Feng, W. Y. Xing, J. J. Liu, S. L. Qiu, Y. Hu and K. M. Liew (2016) Reinforcement of organo-modified molybdenum disulfide nanosheets on the mechanical and thermal properties of polyurethane acrylate films. Journal/Composites Science And Technology 137 188-195. [In English]
Web link: http://dx.doi.org/10.1016/j.compscitech.2016.11.002
Keywords: HYDROGEN EVOLUTION CATALYSIS; MOS2 NANOSHEETS; LAYERED MATERIALS; ARTIFICIAL NACRE; EXFOLIATED MOS2; NANOCOMPOSITES; GRAPHENE; POLYPROPYLENE; PERFORMANCE; COMPOSITES

Abstract: Molybdenum disulfide (MoS2) nanosheets were non-covalently organo-modified by electrostatically interacting with cetylpyridinium chloride (CPC) and then were used to reinforce the properties of polyurethane acrylate (PUA) resin for the first time. Benefited from the alkyl chain of CPC, the modified MoS2 nanosheets can be well dispersed in PUA matrix. Notably, inclusion of 03 wt% CPC-MoS2 leads to a 11.7 degrees C increase in the temperature corresponding to 50 wt % weight loss, indicating the enhanced thermal stability of PUA nanocomposites. Moreover, the improvement in tensile strength, work of fracture and storage modulus (at -75 degrees C) of PUA/f-MoS2 nanocomposites can reach up to 37.4%, 41.9% and 102.0% respectively. This substantial nano-reinforcement is mainly attributed to the proper organic modification and inherent feature of MoS2 nanosheets. The strong interfacial adhesion within PUA/f- MoS2 nanocomposites can efficiently transfer the load from weak polymer chains to robust MoS2 nanosheets. (C) 2016 Elsevier Ltd. All rights reserved.