Xu WZ, Lu B, Hu Y, Song L, Nie SB (2012) Synthesis and characterization of novel fluorinated polyurethane elastomers based on 2,2-bis 4-(4-amino-2-trifluoromehyloxyphenyl) phenyl propane. Polymers for Advanced Technologies 23(5), 877-883. [In English]
Web link: http://dx.doi.org/10.1002/pat.1983
Keywords: fluorinated diamine; fluorinated polyurethane elastomer; surface; properties; flame retardancy; segmented polyurethanes; chain extenders; phosphine oxide; surface; polyimides
Abstract: 2,2-Bis[4-(4-amino-2-trifluoromehyloxyphenyl) phenyl]propane (BAFPP) was synthesized based on 2-chlorobenzotrifluoride and bisphenol A and characterized by Fourier transform infrared spectroscopy and nuclear magnetic resonance. BAFPP was used as a chain extender to prepare a series of fluorine-containing polyurethane elastomers (FPUEs) with different fluorine contents by changing the soft segments and isocyanate index (R). The FPUEs were investigated by water absorption, contact angle, X-ray photoelectron spectroscopy, thermogravimetric analysis, and microscale combustion calorimetry. The results show that the FPUEs prepared from BAFPP were elastomers that have low surface tension, low water absorption, and good thermal stability. Furthermore, FPUEs also exhibit good flame resistance, and the peak heat release rate of FPUE based on BAFPP (282.9 282.9W/g) is much lower than that of polyurethane elastomer without the F element (537.2W/g). Copyright (C) 2011 John Wiley & Sons, Ltd.