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Xing WY, Hu Y, Song L, Chen XL, Zhang P, Ni JX (2009) Polymer Degradation and Stability 94(7), 1176-1182.
文章来源:WOS    作者:SKLFS    发布时间:2011-08-16

Xing WY, Hu Y, Song L, Chen XL, Zhang P, Ni JX (2009) Thermal degradation and combustion of a novel UV curable coating containing phosphorus. Polymer Degradation and Stability 94(7), 1176-1182. [In English]

Web link: http://dx.doi.org/10.1016/j.polymdegradstab.2009.02.014

Keywords:

UV-curing; Phosphorus; Thermal degradation; Combustibility; TG-IR; flame-retardant coatings; behavior; phosphate; polymer; mechanism; photopolymerization; kinetics; resins; epoxy

Abstract: A novel phosphorus monomer (BDEEP) has been synthesized by allowing phosphorus oxychloride to react with 2-hydroxyethyl acrylate (HEA) and 1,4-Butane diol. Its structure was characterized by Fourier transformed infrared spectroscopy (FTIR) and (1)H nuclear magnetic resonance spectroscopy ((1)H NMR). The UV-curing behavior was investigated by FTIR. The combustibility was examined by microscale combustion colorimeter (MCC). The heat release rate (HRR) and heat release capacity (HRC) are 42.1 w/g and 44.0 J/gK, respectively. The thermal degradation was characterized using thermogravimetric analysis/infrared spectrometry (TG-IR). The curve of TGA indicates that there are three characteristic degradation temperature stages for the cured film, which was further characterized by real time Fourier transform infrared (RTFTIR) measurement. It is proposed that the flame retardant action results from decomposition of phosphate to form poly(phosphoric acid), which catalyses the breakage of bonds adjacent to carbonyl groups to form the char, preventing the sample from burning further. The volatilized products formed on thermal degradation of BDEEP indicated that the volatilized products are CO, CO(2), water, alkane, carbonyl, phosphorus compounds and aromatic compounds according to the temperature of onset formation. (C) 2009 Elsevier Ltd. All rights reserved.

 
 
相关链接
Xing WY, Hu Y, Song L, Chen XL, Zhang P, Ni JX (2009) Polymer Degradation and Stability 94(7), 1176-1182.
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